Asymmetric induction by the s-butyl group in cis- and trans-dichloro(benzylamine)(olefin)platinum(II) complexes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1164-1166
- https://doi.org/10.1039/c29700001164
Abstract
In cis- and trans-dichloro[CH:CH·(CH2)n·[graphic omitted]H(Me)Et](benzylamine)platinum(II) complexes, the asymmetric carbon atom originally present in the olefin induces the opposite absolute configuration in the tertiary carbon atom bound to Pt and, at least in the cis-complexes, the extent of asymmetric induction rapidly diminishes with increasing n.Keywords
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