Chemistry of 2-substituted adamantanes. II. Preparation of 2-adamantanethiol and some of its derivatives. Aromatic solvent-induced shifts in their n.m.r. spectra
- 15 November 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 48 (22) , 3593-3597
- https://doi.org/10.1139/v70-602
Abstract
Reduction (NaBH4) of adamantanethione gives high yields of pure 2-adamantanethiol, from which several derivatives including the methyl sulfide, sulfoxide, and sulfone were prepared. The sulfenyl chloride was prepared and used insitu. From the n.m.r. spectra the aromatic solvent-induced shifts Δ = τ(benzene) – τ(CCl4 or CDCl3) were determined, where possible.Keywords
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