Chiral discrimination in the intramolecular abstraction of allylic hydrogens by benzophenone triplets
- 3 June 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1592-1593
- https://doi.org/10.1039/b303263a
Abstract
Using two diastereomeric compounds containing benzophenone and olefin units, significant chiral discrimination has been found in all the photophysical and photochemical processes involved in intramolecular hydrogen abstraction: overall quenching of benzophenone triplets, actual hydrogen abstraction step and π-quenching.Keywords
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