Bridging by adsorbed polymers between two surfaces
- 15 November 1994
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 101 (10) , 9181-9194
- https://doi.org/10.1063/1.468448
Abstract
We analyze the adsorption of flexible polymers between two parallel plates separated a distance 2l. We consider a semidilute polymer solution in contact with the two adsorbing walls and describe the statistics of bridges and loops. A detailed mean‐field calculation allows us to obtain the size and density of bridges in two regimes: l≳ξ and l<ξ, where ξ is the bulk correlation length, as well as the size of loop and train sequences. These results are compared with a scaling analysis performed in the spirit of the self‐similar profile introduced by de Gennes.Keywords
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