Siliciumverbindugen mit starken intramolekularen sterischen Wechselwirkungen, XV [1]. Cycloadditionsprodukte des Tetra-tert-butyldisilens / Silicon Compounds with Strong Intramolecular Steric Interactions, XV [1]. Cycloaddition Products of Tetra-tert-butyldisilene
Open Access
- 1 December 1983
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 38 (12) , 1695-1696
- https://doi.org/10.1515/znb-1983-1225
Abstract
The reaction of 1,1,2,2-tetra-tert-butyl-1,2- dihalodisilanes with alkali metals or metal naphthalenides leads to a complex reaction mixture from which one compound has been identified by its GC/mass spectrum as tetra-tert-butyldisilene (1). The constitution of 1 has been further confirmed by its cycloaddition products with benzil or 1,3-cyclohexadiene, respectivelyKeywords
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