Biphasic photochemistry: use of the barton reaction to determine micelle microviscosity
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1110-1111
- https://doi.org/10.1039/c39780001110
Abstract
The Barton reaction–the photolysis of alkyl nitrites–has been used to determine the microviscosity of a micelle core using a reciprocal relationship found between the ratio of hydroxy-ketone to ketone formed and the macroviscosities of solvents in homogeneous solution.Keywords
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