Dependence of the optical properties of semiconductor alloys on the degree of long-range order

Abstract
Many III-V semiconductor alloys exhibit spontaneous [111] alternate monolayer ordering when grown from the vapor phase. This is manifested by the splitting of the valence-band maximum and by a reduction in the direct band gap. We show here how these features can be used to deduce quantitatively the degree of long-range order in a given sample. Examples are given for Ga0.5In0.5P and Ga0.5In0.5As alloys.