Assignment of finely resolved 13C NMR spectra of polyacrylates
- 1 October 1995
- journal article
- research article
- Published by Wiley in Macromolecular Chemistry and Physics
- Vol. 196 (10) , 3415-3424
- https://doi.org/10.1002/macp.1995.021961026
Abstract
13C NMR spectra of poly(methyl acrylate) (PMA), poly(ethyl acrylate) (PEA), poly(isopropyl acrylate) (PIPA), poly(butyl acrylate) (PBA), and poly(isobutyl acrylate) (PIBA) with various tacticities were determined. It was found that methine carbon resonances of PIPA split into triad sequences and those of PEA, PBA and PIBA show a mm triad at high field. Methylene carbon spectra of polyacrylates were assigned in terms of hexad sequences using HECTOR (13C‐1H COSY) spectra.Keywords
This publication has 13 references indexed in Scilit:
- 13C nuclear magnetic resonance spectra of polyacrylates and their model compoundsJournal of Polymer Science: Polymer Chemistry Edition, 1973
- Stereoregularity of poly(isopropyl acrylate) and its racemization during hydrolysisJournal of Polymer Science Part A-1: Polymer Chemistry, 1972
- Stereoregularity of radically polymerized poly(alkyl acrylates) and poly(trimethylsilyl acrylates) and the preparation of syndiotactic poly(methyl acrylate)Journal of Polymer Science Part A-1: Polymer Chemistry, 1971
- Stereoregularity of poly(methyl acrylate)Journal of Polymer Science Part A-1: Polymer Chemistry, 1967
- Stereoregularily and reaction of polyacrylates and polyacrylonitrilesJournal of Polymer Science Part C: Polymer Symposia, 1967
- Stereoregular Modes of Double Bond Opening Determined in the Initial Short Period of the Anionic Polymerization of Isopropyl AcrylateJournal of the American Chemical Society, 1966
- Two Diisotactic Processes in the Anionic Polymerization of Isopropyl Acrylate with Phenylmagnesium BromideJournal of the American Chemical Society, 1965
- trans Opening of Monomer Double Bonds in Anionic Polymerization of Methyl Acrylate Initiated by Lithium Aluminum HydrideJournal of the American Chemical Society, 1965
- On the Propagation Steps of Free-Radical and Anionic PolymerizationJournal of the American Chemical Society, 1964
- Stereospecificity in the Anionic Polymerization of Isopropyl AcrylateJournal of the American Chemical Society, 1964