The Equation of State of Frozen Neon, Argon, Krypton, and Xenon
- 1 August 1939
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 7 (8) , 603-614
- https://doi.org/10.1063/1.1750498
Abstract
The interaction between two rare gas atoms is assumed to have the form — Ar—6+AB(exp—r/ρ). The values of A and B are found from the lattice distances and the heats of sublimation of frozen neon, argon, krypton and xenon for ρ=0.2091A and ρ=0.345A. The equations of state of the solids are then calculated, including the Debye θ's and the breakdown points, which occur a few degrees below the melting points. For krypton, the expansion coefficient and the specific heat are calculated, but are found too high at higher temperatures.Keywords
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