Pulse radiolysis of penicillamine in aqueous solution: the thiyl radical and the disulphide radical anion
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1163-1165
- https://doi.org/10.1039/c29710001163
Abstract
The RS· radical and the RSSR– radical anion of penicillamine have λmax 330 nm, ε330 1·22 × 103 M –1 cm–1 and λmax 450 nm, ε450 7·5 × 103 M –1 cm–1, respectively, and K1 for the equilibrium, RS·+ RS–⇄ RSSR– is 2·5 × 102 M –1 at pH 8.Keywords
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