A regioselective, stereoselective synthesis of a diacylglycerophosphocholine hydroperoxide by use of lipoxygenase and lipase
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1281-1282
- https://doi.org/10.1039/c39900001281
Abstract
1-Stearoyl-2-[13′-(S)-hydroperoxy-(9′Z, 11′E)-octadecadienoyl]-sn-glycero-3-phosphocholine (11) was synthesized without contamination by any regio- and stereo-chemical isomers by a combination of lipoxygenase-catalysed peroxidation, lipase-catalysed stearoylation, and dicyclohexyl carbodiimide-mediated (DCC) esterification.Keywords
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