A Novel Three-Dimensional Cyano-Linked Metal-Complex Host Clathrate [{Cd(imH)}{Cd(CN)3(imH)}{Cd(CN)3}]·C6H6 (imH = imidazole): X-Ray Single Crystal Structure and Solid State 113Cd and 2H NMR
- 1 January 1996
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (1) , 89-90
- https://doi.org/10.1246/cl.1996.89
Abstract
The title clathrate involves imidazole-ligated octahedral and tetrahedral Cd atoms along with CN-only-ligated tetrahedral Cd linked by CN bridges to one another to give a three-dimensional host framework in which the guest benzene molecule takes a uniaxial reorientational motion about the molecular sixfold axis.Keywords
This publication has 3 references indexed in Scilit:
- Crystal structure of Cd5(CN)10(H2O)4.cntdot.4C6H11OH studied by x-ray diffraction and solid-state cadmium-113 NMR. A new type of cristobalite-like framework host with a site interacting with cyclohexanol by hydrogen bondingJournal of the American Chemical Society, 1992
- Solid-state deuteron and proton NMR of guest and host motions in the Hofmann-type and related benzene clathratesThe Journal of Physical Chemistry, 1991
- 113Cd NMR studies of Hofmann-type clathrates and related compounds: Evidence for two room temperature orientational glassesCanadian Journal of Chemistry, 1990