Transition-metal nitrosyl compounds. Dibromodinitrosylmolybdenum, dibromodinitrosyltungsten, di-iododinitrosylmolybdenum, and some of their derivatives
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 475-478
- https://doi.org/10.1039/j19670000475
Abstract
Molybdenum or tungsten hexacarbonyl react with nitrosyl bromide to give dibromodinitrosylmolybdenum or dibromodinitrosyltungsten. Di-iododinitrosylmolybdenum has also been prepared. These compounds readily react with ligands (L) to give the monomeric octahedral complexes M(NO)2Br2L2, where L = triphenylphosphine, triphenylarsine, or pyridine. The reaction of the Mo(NO)2X2 with tetra-alkylammonium salts give compounds of the type [Mo(NO)2X4][R4N]2(X = Br, R = Et; X = I, R = Bun).Keywords
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