The activation of C–H bonds in cyclopentane by bis(phosphine)rhenium heptahydrides

Abstract
In the presence of 3,3-dimethylbut-1-ene, the complexes L2ReH7(L = PPh3 or PEt2Ph) dehydrogenate cyclopentane, giving the dihydrido-cyclopentadienyl compounds L2(η5-C5H5)ReH2.

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