Materials chemistry communications. Synthesis and optical spectroscopy of monomeric and polymeric cobalt σ-acetylide complexes
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 2 (7) , 759-760
- https://doi.org/10.1039/jm9920200759
Abstract
Optical spectra of the complexes, trans-ClCoN4CCC6H5, trans-CoN4(CCC6H5)2 and [graphic omitted]CoN4CC-p-C6H4CC[graphic omitted]n, (where N4= 3,9-dimethyl-4,8-diazaundecane-2,10-dione dioxime) show absorptions associated with π-π* transitions of the acetylenic unit and indicate an extended π-electron conjugation through the metal sites on the chain in the polymeric complex.Keywords
This publication has 13 references indexed in Scilit:
- Di-, tri-, pseudo-di- and pseudo-tetra-acetylenic polymers of platinum: Synthesis, characterization and optical spectraJournal of Organometallic Chemistry, 1992
- Synthesis of monomeric, oligomeric and polymeric σ-acetylide complexes of platinum, palladium, nickel and rhodiumJournal of Organometallic Chemistry, 1992
- Synthesis of mononuclear and oligomeric ruthenium(II) acetylidesJournal of Organometallic Chemistry, 1991
- Synthesis of novel rigid rod iron metal containing polyyne polymersJournal of Organometallic Chemistry, 1991
- Synthesis of linked metal acetylide complexes for nonlinear opticsJournal of Organometallic Chemistry, 1991
- Non-linear optical properties of Group 10 metal alkynyls and their polymersJournal of Materials Chemistry, 1991
- Synthesis and optical spectroscopy of platinum-metal-containing di- and tri-acetylenic polymersJournal of Materials Chemistry, 1991
- Synthesis of monomeric and oligomeric bis(acetylide) complexes of platinum and rhodiumJournal of the Chemical Society, Chemical Communications, 1991
- Studies on polyyne polymers containing transition metals in the main chain. VII. Synthesis and characterization of palladium‐polyyne polymersJournal of Polymer Science: Polymer Chemistry Edition, 1982
- Linear polymers containing transition metals in the main chainPublished by Springer Nature ,1981