A novel synthetic metal catalytic system for dehydrogenative oxidation based on redox of polyaniline
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 194-195
- https://doi.org/10.1039/c39930000194
Abstract
Polyaniline serves as a synthetic metal catalyst with reversible redox under oxygen to induce dehydrogenative and/or decarboxylative oxidation of benzylamines and 2-phenylglycine into the corresponding imines and, in combination with copper(II) chloride or iron(III) chloride, dehydrogenation of cinnamyl alcohol into cinnamaldehyde possibly due to complexation.Keywords
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