A fluxional tetraplatinum cluster: solution and solid state structure of the cation [Pt4(µ-H)(µ-CO)2(µ-Ph2PCH2PPh2)3(Ph2PCH2PPh2)]+
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 149-150
- https://doi.org/10.1039/c39880000149
Abstract
The 58-electron cationic cluster complex [Pt4(µ-H)(µ-CO)2(µ-dppm)3(dppm-P)]+, dppm = Ph2PCH2PPh2, has been characterized in solution by n.m.r. spectroscopy and in the solid by X-ray analysis of the PF6 – salt; the cation displays novel fluxionality with rapid rotation of a µ-H below and a µ-Pt(CO)2(dppm-P) unit above a Pt3(µ-dppm)3 + triangle.Keywords
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