Homologous series of liquid-crystalline metal free and copper octa-n-alkoxyphthalocyanines

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Abstract
Two series of discotic liquid crystals, one based on metal-free and the other on copper containing phthalocyanine (Pc) as the central core and eight peripherally n-alkoxy groups (C6–C12) as substituents have been synthesized and their mesomorphic properties and structural parameters have been determined. These compounds represent a series totally devoid of polymorphism, the mesophase in all cases being Dho. In the solid state an orthorhombic two dimensional lattice with four molecules per unit cell and a presumably tilted stacking is present, while in the mesophase the planes of the molecules are on average perpendicular to the direction of the stacks. The aggregation behaviour of the C8, C10 and C12 homologues was studied as a function of solvent polarity and of concentration. The electrical properties of the copper complexes of the n-dodecoxy and n-octoxy derivatives have been determined by means of complex impedance spectroscopy and compared with those of the non-mesogenic CuPc.