Synthesis and X-ray crystal structure of the first manganese(II) dialkylamido complex: {Mn3(µ-NEt2)6(µ-Cl)2[Li(THF)2]2}·(C7H16)(THF = tetrahydrofuran)
- 1 January 1989
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 801-802
- https://doi.org/10.1039/c39890000801
Abstract
Reaction of MnCl2 with LiNEt2 in tetrahydrofuran(THF)/n-heptane afforded the pentanuclear title complex {Mn3(µ-NEt2)6(µ-Cl)2[Li(THF)]2}, whose molecular structure shows the presence of three tetrahedrally co-ordinated manganese atoms, joined by four bridging NEt2 groups [with Mn–N bond distances ranging from 2.089(4) to 2.203(4)Å, the Mn ⋯ Mn distance being 2.917(1)Å], and two Li(THF)2 moieties terminally bonded via diethylamido and chloride bridges.Keywords
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