Autocatalysis and free radical mechanism in a ruthenium cluster catalysed hydrogen transfer reaction
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1506-1508
- https://doi.org/10.1039/c39900001506
Abstract
The mechanisms of the [(Ph3P)2N][H3Ru4(CO)12]1 catalysed disproportionation and transfer-hydrogenations of cyclohex-2-en-1-one have been shown to involve free radicals; in the latter reaction 1 is converted to other carbonyl species via autocatalysis.Keywords
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