Concurrent crystallization in polypropylene/nylon‐6 blends using maleic anhydride grafted polypropylene as a compatibilizing agent
- 1 June 1994
- journal article
- Published by Wiley in Journal of Polymer Science Part B: Polymer Physics
- Vol. 32 (8) , 1427-1435
- https://doi.org/10.1002/polb.1994.090320814
Abstract
This paper describes the nonisothermal crystallization of molten blends of two semicrystalline polymers, polypropylene (PP) and Nylon‐6 (N6). A discussion details the effect of the concentration of the compatibilizing agent, maleic anhydride grafted polypropylene (MAH‐g‐PP), on the crystallization behavior. The crystallization thermograms showed one crystallization peak or two crystallization peaks, which were significantly affected by the presence of MAH‐g‐PP. The crystallization temperature of N6 levels off down as the concentration of MAH‐g‐PP increases, whereas that of PP stays at a roughly constant temperature. These blends containing the compatibilizing agent exhibited concurrent crystallization at the crystallization temperature of PP. The crystallization behavior are also studied by optical microscopy under crossed polarizers. © 1994 John Wiley & Sons, Inc.Keywords
This publication has 22 references indexed in Scilit:
- Assessing polymer crystallizability from nonisothermal crystallization behaviorAdvances in Polymer Technology, 1993
- Blends of polypropylene and nylon 6: Influence of the compatibilizer, molecular weight, and processing conditionsAdvances in Polymer Technology, 1993
- Dynamic mechanical properties of polypropylene–polyamide blends: Effect of compatibilizationJournal of Applied Polymer Science, 1992
- Structure‐property‐processing relationships of polypropylene‐polybutylene blendsPolymer Engineering & Science, 1987
- Formation of dispersed phase in incompatible polymer blends: Interfacial and rheological effectsPolymer Engineering & Science, 1987
- Influence of composition, crystallization conditions and melt phase structure on solid morphology, kinetics of crystallization and thermal behavior of binary polymer/polymer blendsPolymer Engineering & Science, 1984
- Polypropylene/nylon 6 blends: Phase distribution morphology, rheological measurements, and structure development in melt spinningJournal of Applied Polymer Science, 1983
- Crystallization of crystalline/crystalline blends: Polypropylene/polybutene-1Journal of Applied Polymer Science, 1982
- Crystalline/crystalline polymer blends: Some structure–property relationshipsJournal of Applied Polymer Science, 1979
- Studies on polymer blend of nylon 6 and polypropylene or nylon 6 and polystyrene using the reaction of polymerJournal of Applied Polymer Science, 1974