Novel fulleropyrrolidinium‐based materials
- 14 January 2000
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 10 (2) , 269-273
- https://doi.org/10.1039/a903494c
Abstract
The cyclic voltammetry of a series of soluble N-methylfulleropyrrolidinium salts shows that these materials are better electron-acceptors than unmodified C60. The stability of mono-reduced, zwitterionic, and doubly-reduced anionic species, produced either electrochemically or chemically, has been checked by absorption spectroscopy. Langmuir–Blodgett (LB) layers of the C60 derivatives mixed with tricosanoic acid have been built up on different substrates. The optical properties of the films have been characterized using absorption spectroscopy and their structure was investigated by X-ray diffraction.Keywords
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