Diastereo-differentiating hydrogen transfer in 5-deazaflavins
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 457-458
- https://doi.org/10.1039/c39880000457
Abstract
Reduction of 5-deazaisoalloxazinophanes dFl(n) in which N(3) and O(2′α) in the 10-(2-hydroxy)phenyl group were linked by a (CH2)n chain (n= 6,8) resulted in the boat-shaped 1,5-dihydro forms dFlred(n); hydrogen transfer to dFl(n) and from dFlred(n) occurred exclusively at the axial C(5) position.Keywords
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