An efficient synthetic route to primary and secondary condensation products of silanetriols starting from (arylamino)trichlorosilanes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2417-2418
- https://doi.org/10.1039/cc9960002417
Abstract
Stoichiometry dependent hydrolysis of (arylamino)-silyltrichlorides using anhydrous N2H4 as the HCl acceptor and dehydrating agent leads to the formation of the primary and secondary condensation products of silanetriols, tetrahydroxydisiloxanes [Ar(SiMe3)NSi(OH)2]2O and cyclotrihydroxytrisiloxanes [Ar(SiMe3)NSi(OH)O]3, respectively.Keywords
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