A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex
- 23 November 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2435-2436
- https://doi.org/10.1039/b007059i
Abstract
The X-ray crystal structure and electrochemical data of a manganese complex [L2Mn2 III(μ-O)(μ-AcO)2][ PF6]2 with L being an enantiopure C3-symmetric 1,4,7-triazacyclononane derived from L-proline are compared to those of [Me3- TACN2Mn2 III(μ-O)(μ-AcO)2 ][PF6]2; catalytic studies reveal the applicability of the complex in enantioselective epoxidations.Keywords
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