A common aziridinium ion intermediate in the solvolysis of halogeno-codeinone and -neopinone acetals
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1121-1122
- https://doi.org/10.1039/c29710001121
Abstract
Treatment of the dimethyl acetal of either 14-bromocodeinone or 7-iodoneopinone with silver perchlorate in benzene gives an aziridinium salt believed to be an intermediate leading to 9-substituted indolinocodeinone derivatives in the solvolysis of either acetal.Keywords
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