Substituent and solvent effects on organic acids: an electrostatic theory
- 15 April 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (8) , 1296-1299
- https://doi.org/10.1139/v76-183
Abstract
We have used an electrostatic model as basis for derived equations to represent the effects of substituents and solvents on the thermodynamics of proton transfer reactions. Equations derived in this manner are related to those based on earlier 'internal-environmental' models and are also discussed in relation to recent gas phase acidity work.Keywords
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