Rearrangements of cyclopropylmethyl and but-3-enyl cobaloximes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 954-956
- https://doi.org/10.1039/c39780000954
Abstract
[1-13C]-1-Cyclopropylmethyl(pyridine)cobaloxime (1b) rearranges (in CDCl3 at 310 K) to [4-13C]-but-3-enyl(pyridine)cobaloxime (2b); 1-methylbut-3-enyl(pyridine)cobaloxime (3) rearranges to 2-methylbut-3-enyl(pyridine)cobaloxime (4) under the catalytic influence of trifluoroacetic acid in CDCl3.Keywords
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