Enantioselective synthesis of an ant venom alkaloid (–)-[3S-(3β, 5β 8α)]-3-heptyl-5-methylpyrrolizidine
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1172-1174
- https://doi.org/10.1039/c39830001172
Abstract
An ant venom alkaloid (–)-[3S-(3β, 5β, 8α)]-3-heptyl-5-methylpyrrolizidine (1) has been synthesized in an enantioselective fashion from 3-(5-methyl-2-furly)propionaldehyde (2) employing enantioselective epoxidation at the key stage.Keywords
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