Electrochemical Generation of C-N-C 1,3-Dipole Leading to Pyrrolidine Skeleton

Abstract
Electrochemical oxidation of N,N-bis(TMSmethyl)benzyl amine in a DMF/AcONa/(C)-(C) system using an undivided cell at room temperature generated a C-N-C 1,3-dipole, which underwent cycloaddition with electron deficient olefins to give pyrrolidine derivatives.

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