Base hydrolyses of penta-ammineruthenium(III) complexes of organonitriles
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 795-796
- https://doi.org/10.1039/c39740000795
Abstract
Base hydrolysis of the Ru(NH3)5 3+ complex of acetonitrile to the corresponding complex of the acetamide anion occurs with a rate ca. 108 as fast as the free ligand, ca. 106 as fast as the analogous RuII complex, and more than 102 faster than the RhIII analogue.Keywords
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