Topological isomerism in the formation of a novel three-dimensional metal-organic polycatenane

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Abstract
The self-assembly of cadmium nitrate with sodium dicyanamide and 1,3-bis(4′-pyridyl)propane generates a kinetic 1D isomer and a thermodynamic 2D isomer, which presents an unusual pattern of 3D supramolecular entanglement.

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