The precipitation of sparingly‐soluble acid, neutral and basic metal salts from aqueous solution: Ionic equilibria at different pHs, precipitate phases and precipitation mechanisms

Publisher Website
Google Scholar
Abstract
The precipitations of the sparingly‐soluble acid, neutral and basic salts of the divalent cations beryllium, magnesium, calcium, strontium, barium, manganese (II), iron (II), cobalt (II), nickel (II), copper (II), zinc, cadmium, mercury (II), tin (II) and lead (II) with the inorganic anions sulphate, chromate, molybdate, monohydrogen phosphate, phosphate, and carbonate (from supersaturated aqueous solutions) are surveyed. The different types of ionic equilibria (cation hydrolysis, anion hydrolysis, ion‐pair formation) that may influence these precipitations, at different pHs and ionic concentrations, are examined. The crystalline phases precipitated at different pHs are tabulated and the precipitation mechanisms (at different pHs) are analysed.

This publication has 38 references indexed in Scilit: