Search for a General Route to Metallaboranes via the Reaction of Monocyclopentadienyl Metal Chlorides with Monoborane. Synthesis and Reactivity of the Rhodaboranenido-1-Cl-2,3-{(η5-C5Me5)Rh}2B3H6
- 1 March 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 120 (11) , 2686-2687
- https://doi.org/10.1021/ja974268a
Abstract
No abstract availableThis publication has 23 references indexed in Scilit:
- Cp*TaCl2B4H8: synthesis, crystal structure and spectroscopic characterization of an air-stable, electronically unsaturated, chiral tantalaboraneChemical Communications, 1998
- Reactions of an Electronically Unsaturated Chromaborane. Coordination of CS2 to (η5-C5Me5)2Cr2B4H8 and Its Hydroboration to a Methanedithiolato LigandOrganometallics, 1996
- Synthesis of Cobaltaborane Clusters from [Cp*CoCl]2 and Monoboranes. New Structures and Mechanistic ImplicationsOrganometallics, 1994
- Cluster chemistry driven by ligand bulk. Significance of the synthesis of nido-1-(.eta.5-C5Me5)Co-2-(.eta.4-C5Me5H)CoB3H8 and its dehydrogenation to nido-2,4-{(.eta.5-C5Me5)Co}2B3H7Journal of the American Chemical Society, 1993
- Metallacarboranes in catalysis. 8. I: Catalytic hydrogenolysis of alkenyl acetates. II: Catalytic alkene isomerization and hydrogenation revisitedJournal of the American Chemical Society, 1989
- Pentamethylcyclopentadienylrhodaborane chemistry. Part 3. The reaction of [{Rh(η5-C5Me5)Cl2}2] with closo-[B10H10]2–and arachno-B10H12-6,9-(PMe2Ph)2, and the characterisation of some novel rhodaboranes by X-ray diffraction analysis and nuclear magnetic resonance spectroscopyJ. Chem. Soc., Dalton Trans., 1987
- Metal atom synthesis of metallaboron clusters. 1. Direct synthesis of cobaltaborane and cobaltacarborane complexesInorganic Chemistry, 1980
- Studies of 2-(.eta.5-C5H5)CoB4H8, a cobaltaborane analog of pentaborane(9)Inorganic Chemistry, 1978
- Structures of metalloboron clusters. X-ray studies of octahedral (.eta.5-C5H5)3Co3B3H5 and capped octahedral (.eta.5-C5H5)3Co3B4H4, a boron analog of tricobalt carbon clustersInorganic Chemistry, 1977
- Polyhedral cobaltaboranes. Versatile replacement of borane(1) groups by (.eta.5-cyclopentadienyl)cobalt units in boron hydride frameworks. Borane-metal cluster hybrid moleculesJournal of the American Chemical Society, 1977