Use of a Tensammetric Wave for the End-Point Detection in Chelatometry
- 1 January 1972
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 5 (10) , 723-728
- https://doi.org/10.1080/00032717208064353
Abstract
A new method for the end-point detection in complexometric titration using a tensammetric wave of organic reagents such as oxine and alizarin complexone (ALC) was studied. The tensammetric wave of these reagents disappears by their chelate formation and reappears by the liberation of free indicator during the exchange reaction between indicator chelate and EDTA. This mechanism is utilized for the end-point detection in complexometric titration of metals. Since the sensitivity of tensammetric wave is extremely high, very sharp end-point can be obtained for the titration of metals even in the concentration of 10−5M.Keywords
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