Oscillatory CO oxidation on Pt(110): Modeling of temporal self-organization

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Abstract
The parameters entering the kinetics for the mechanism of catalytic CO oxidation have been adapted for a Pt(110) surface, giving rise to a two‐variable model correctly predicting bistability. Oscillations are obtained when, in addition, the adsorbate‐driven 1×2–1×1 structural phase transition of Pt(110) is taken into account. Mixed‐mode oscillations can be qualitatively explained by including the faceting of the surface as a fourth variable. The limitations of the model essentially stem from the fact that only ordinary differential equations have been analyzed so far neglecting spatial pattern formation. It is discussed which dynamic phenomena observed experimentally in the CO oxidation on Pt(110) will probably not be adequately describable without taking spatial effects into account.