Preparation and infrared spectroscopic characterization of some (oxy-diacetato)uranyl(VI) complexes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1308-1311
- https://doi.org/10.1039/dt9730001308
Abstract
Polymeric complexes, [UO2(oda)]n(oda = oxydiacetate, O2CCH2OCH2CO2 2–, n=∞), have been prepared, from the reaction of uranyl(VI) ions and oxydiacetic acid or its disodium salt, and characterized, mainly by i.r. spectroscopy. The complex Na2[UO2(oda)2],nH2O (n= 2 or 3) was obtained when an excess of the ligand was used in the reaction. In the presence of pyridine N-oxide(Opy), both monomeric [UO2(oda)(Opy)2] and polymeric [UO2(oda)-(Opy)]n(n=∞) complexes were obtained.Keywords
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