Synthesis and electrochemical properties of some metallated and peripherally substituted porphyrin co-facial dimers
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 2395-2402
- https://doi.org/10.1039/p19870002395
Abstract
The high dilution coupling of mesoporphyrin-II bis(acid chloride) with a diol derived from mesoporphyrin-II bis(methyl ester) yields two diastereoisomers of a co-facial porphyrin dimer. The use of zinc as a removable protecting group for the diol face gives access to a wide range of mixed metal and mixed valence co-facial porphyrin dimers.Introduction of ami and nitro peripheral substituents provides another method for altering independenty the properties of each of the prophyrin faces in a dimer.This publication has 6 references indexed in Scilit:
- Artificial allosteric system. 2. Cooperative 1-methylimidazole binding to an artificial allosteric system, zinc-gable porphyrin-dipyridylmethane complexJournal of the American Chemical Society, 1985
- Synthesis and geometry determination of cofacial diporphyrins. EPR spectroscopy of dicopper diporphyrins in frozen solutionJournal of the American Chemical Society, 1985
- Photoinduced electron-transfer reactions in a chlorophyllide-pheophorbide cyclophane. A model for photosynthetic reaction centersJournal of the American Chemical Society, 1983
- Energies and kinetics of radical pairs involving bacteriochlorophyll and bacteriopheophytin in bacterial reaction centersProceedings of the National Academy of Sciences, 1981
- Role of the chlorophyll dimer in bacterial photosynthesisProceedings of the National Academy of Sciences, 1980
- Synthesis of covalently linked porphyrin dimers and trimersJournal of Heterocyclic Chemistry, 1976