Anion-templated formation of a unique inorganic ‘super-adamantoid’ cage [Ag6(triphos)4(O3SCF3)4]2+ [triphos = (PPh2CH2)3CMe]
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2323-2324
- https://doi.org/10.1039/a806388e
Abstract
In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual ‘endo-methyl’ geometry of the triphos ligands.Keywords
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