Is it possible to stabilise complexes with a tungsten–phosphorus triple bond?
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1671-1672
- https://doi.org/10.1039/c39950001671
Abstract
[W(CO)2{η4-(But 2C2P2)W(CO)5}{η-2-(ButCP)W(CO)5}]1 is prepared by treatment of ButCP with [W(CO)5THF]; the reaction of [W2(OBut)6] with ButCP in the presence of [M(CO)5THF](M = Cr, W) affords novel compounds of the type [(ButO)3WP→M(CO)5](M = Cr, W), the first examples of a formal WP containing complex.Keywords
This publication has 13 references indexed in Scilit:
- Reaction of Diantimony Anion with Mononuclear Metal Carbonyls. First Observed Instance of an Antimony-Transition-Metal Triple BondJournal of the American Chemical Society, 1995
- Px ligands with a maximum of electron-donating ability: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF]Journal of Organometallic Chemistry, 1993
- The Formation of cyclo‐P4 Ligands with Maximum Electron Donor AbilityAngewandte Chemie International Edition in English, 1992
- The cyclo‐P4 Ligand as 12‐Electron DonorAngewandte Chemie International Edition in English, 1991
- Arsen‐Cobalt‐Molybdän‐Cluster durch photolytische und thermische Reaktion von μ3‐AsCp3Mo3(CO)6 mit CpCo(CO)2European Journal of Inorganic Chemistry, 1989
- Coordination chemistry of compounds containing phosphorus-carbon multiple bondsChemical Reviews, 1988
- A phosphido-capped tritungsten alkoxide cluster: W3(.mu.3-P)(.mu.-OCH2-tert-Bu)3(OCH2-tert-Bu)6 and speculation upon the existence of a reactive (tert-BuCH2O)3W.ident.P intermediateInorganic Chemistry, 1988
- λ 3 ‐1,3‐Diphosphacyclobutadiene‐Cobalt Complexes by Cyclodimerization of λ 3 ‐PhosphaalkynesEuropean Journal of Inorganic Chemistry, 1988
- (η3-P3)W(OCH2But)3(HNMe2) formed by cleavage of the WW bond in the reaction between W2(OCH2But)6(HNMe2)2 and P4Inorganica Chimica Acta, 1987
- Alkylidynephosphines - Syntheses and ReactivityPhosphorus and Sulfur and the Related Elements, 1987