π-Cyclopentadienylmanganese Thiocarbonyl Complexes

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Abstract
The complete series of thiocarbonyl complexes, π-C5H5Mn(CO)3−x(CS)x(x = 1, 2, 3), have been prepared by reaction of the appropriate cis-cyclooctene derivative, π-C5H5Mn(CO)3−x(CS)x−1(C8H14), with CS2 in the presence of triphenylphosphine.