NQR and relaxation at the ferroelectric transition in NaN
- 1 May 1977
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 15 (9) , 4318-4327
- https://doi.org/10.1103/physrevb.15.4318
Abstract
nuclear quadrupole resonance and relaxation measurements in NaN around the ferroelectric transitions have been performed by pulse and Fourier-transform technique, with high-temperature resolution and accuracy. In the narrow temperature range in which the antiferroelectric phase exists and where previous authors failed to detect the nuclear-quadrupole-resonance (NQR) signals, the splitting of the and lines in two components were observed. A theory is developed to connect the NQR parameters to the torsional vibrations of the N ions as well as to the order-disorder reorientational fluctuations driving the transitions. The critical fluctuations are described through a kinematical Ising model. It is proven that the reorientational order-disorder variable is reversed by an angle which is not exactly . By analyzing the experimental results in the light of the theoretical treatment interesting information on the critical dynamics is obtained.
Keywords
This publication has 25 references indexed in Scilit:
- 14N nuclear quadrupole resonance and relaxation measurements of sodium nitriteThe Journal of Chemical Physics, 1976
- On the dynamics of structural phase transitionsJournal of Physics C: Solid State Physics, 1976
- Long-wavelength soft modes, central peaks, and the Lyddane-Sachs-Teller relationPhysical Review B, 1975
- Critical Behavior of Electric Susceptibility in NaNO2Journal of the Physics Society Japan, 1975
- 14N Nuclear Quadrupole Resonance in Ferroelectric Sodium Nitrite NaNO2Journal of the Physics Society Japan, 1974
- Nuclear Quadrupole Relaxation of N14 in Sodium NitriteJournal of the Physics Society Japan, 1972
- Crystal Dynamics and the Ferroelectric Phase Transition of Sodium NitriteJournal of the Physics Society Japan, 1970
- Static Electric Susceptibility and Dielectric Relaxation Time near the Transition Points in NaNO2Journal of the Physics Society Japan, 1970
- N14 nuclear quadrupole resonance in ferroelectric NaNO2Physica Status Solidi (b), 1970
- 14 N nuclear quadrupole resonance in the ferroelectric phase of sodium nitritePhysics Letters A, 1967