Iron(IV) porphyrins from iron(III) porphyrin cation radicals
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1455-1456
- https://doi.org/10.1039/c39840001455
Abstract
The preparation and spectroscopic data of FeTMP(ClO4)2[(1), TMP = 5,10,15,20-tetramesitylporphyrinato] are reported; the reaction of (1) with NaOMe–MeOH gave a new red species, (2), which is indicated to exist (a) as a symmetrically ligated complex with a vacant dx2–y2 iron orbital (1H n.m.r.)and (b) in the iron(IV) state (Mössbauer spectroscopy).Keywords
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