[Ru6(CO)18]2? in NaX zeolite cages: characterization by EXAFS and FTIR spectroscopy
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 507-508
- https://doi.org/10.1039/c39950000507
Abstract
RuIII(NH3)6 in the cages of NaX zeolite is converted in the presence of CO + H2 into [Ru6(CO)18]2–, which is reversibly fragmented and reconstructed under oxidative and reductive conditions, respectively.Keywords
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