Synthesis, Characterization, and Electrochemistry of σ-Bonded Cobalt Corroles in High Oxidation States
- 1 January 1996
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 35 (19) , 5577-5583
- https://doi.org/10.1021/ic960484t
Abstract
The synthesis, electrochemistry, spectroscopy, and structural characterization of two high-valent phenyl σ-bonded cobalt corroles containing a central cobalt ion in formal +IV and +V oxidation states is presented. The characterized compounds are represented as phenyl σ-bonded cobalt corroles, (OEC)Co(C6H5) and [(OEC)Co(C6H5)]ClO4, where OEC is the trianion of 2,3,7,8,12,13,17,18-octaethylcorrole. The electronic distribution in both molecules is discussed in terms of their NMR and EPR spectroscopic data, magnetic susceptibility, and electrochemistry.Keywords
This publication has 54 references indexed in Scilit:
- Synthesis and Electrochemistry of Iron(III) Corroles Containing a Nitrosyl Axial Ligand. Spectral Characterization of [(OEC)FeIII(NO)]n where n = 0, 1, 2, or -1 and OEC is the Trianion of 2,3,7,8,12,13,17,18-OctaethylcorroleJournal of the American Chemical Society, 1994
- First Direct Synthesis of a Corrole Ring From a Monopyrrolic Precursor. Crystal and Molecular Structure of (Triphenylphosphine)(5,10,15-triphenyl-2,3,7,8,12,13,17,18-octamethylcorrolato)cobalt(III)-DichloromethaneInorganic Chemistry, 1994
- Stable highly oxidizing cobalt complexes of macrocyclic ligandsJournal of the American Chemical Society, 1991
- Dimerization of metalloporphyrin .pi. cation radicals. Characterization of two novel dimers: [Zn(OEP.cntdot.)(OH2)]2(ClO4)2 and [Ni(OEP)]2(ClO4)2Inorganic Chemistry, 1990
- Molecular and electronic structure of pyracyleneJournal of the American Chemical Society, 1990
- Synthese von Dipleiadien: ein typischer Fall von „Serendipität”Angewandte Chemie, 1985
- The Structure and Reactivity of Octadehydrocorrins and CorrolesRussian Chemical Reviews, 1983
- Synthesis of Corroles and OctadehydrocorrinsRussian Chemical Reviews, 1980
- A polarographic investigation of some metal tetradehydrocorrinsJournal of Inorganic and Nuclear Chemistry, 1973
- Induced Paramagnetic Ring CurrentsJournal of the American Chemical Society, 1966