Dramatic solvent effects and stereospecificity in allylic sulphinate–sulphone rearrangements
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1470-1472
- https://doi.org/10.1039/c39830001470
Abstract
Dramatic solvent effects were observed in the thermolysis of allyl sulphinates; heating of chiral trans- and cis-allyl sulphinates (S)-(–)-(1a–g) in N,N-dimethylformamide at 90–120 °C provided chiral sulphones (2a–d) in good yields with very high stereospecificity.Keywords
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