Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical
- 17 October 2007
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 48,p. 5244-5246
- https://doi.org/10.1039/b714526h
Abstract
The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.Keywords
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