Synthesis of novel donor–acceptor manganese(I) complexes of ferrocenylacetylene: crystal structure of [(C5H5)Fe(C5H4)CCMn(CO)3{Ph2PCH(Me)CH2PPh2}] which has potential for second-order non-linear optics
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 2589-2590
- https://doi.org/10.1039/dt9940002589
Abstract
Three novel manganese(I) ferrocenylacetylide complexes have been synthesised and characterised and the crystal structure of [(C5H5)Fe(C5H4)CCMn(CO)3{Ph2PCH(Me)CH2PPh2}] has been determined, in which the incorporation of a chiral chelating phosphine leads to crystallisation in the non-centrosymmetric space group P212121.Keywords
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