Samarium(II)-Mediated Reactions of γ,δ-Unsaturated Ketones. Cyclization and Fragmentation Processes
- 19 June 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (14) , 2345-2347
- https://doi.org/10.1021/ol0260472
Abstract
No abstract availableKeywords
This publication has 10 references indexed in Scilit:
- Cyclopropylcarbinyl-Type Ring Openings. Reconciling the Chemistry of Neutral Radicals and Radical AnionsJournal of the American Chemical Society, 2002
- Reduction of α-aryloxy carbonyl compounds with samarium(ii) iodide. A new traceless linker for the solid phase synthesis of carbonyl compoundsChemical Communications, 2002
- Samarium(II)-Mediated 4-exo-trig Cyclization. A Stereocontrolled Approach to the Core of Pestalotiopsin AOrganic Letters, 2001
- Samarium(II)-mediated 4-exo-trig cyclisations of unsaturated aldehydes. A stereoselective approach to functionalised cyclobutanolsJournal of the Chemical Society, Perkin Transactions 1, 2000
- Samarium(II)-mediated 4-exo trig ketyl-olefin cyclisation of unsaturated aldehydes. A general, stereoselective synthesis of functionalised cyclobutanolsPublished by Elsevier ,1999
- On the mechanism of the intramolecular samarium Barbier reaction. Probes for formation of radical and organosamarium intermediatesTetrahedron, 1997
- The crystal structure of a novel complex [Sm(HMPA)3(H20)4]3+3[I−] formed in the reductive cyclodimerization of linear α,β-unsaturated ketones by SmI2Polyhedron, 1996
- Radikalische Cyclisierung von Dienen, IX. Über die Stereoselektivität der radikalischen 4‐exo‐trig‐Cyclisierung von optisch aktiven (2E)‐6‐Oxohex‐2‐ensäureestern mit Samarium(II)‐iodidEuropean Journal of Inorganic Chemistry, 1994
- Samarium(II) iodide promoted radical ring opening reactions of cyclopropyl ketonesTetrahedron Letters, 1991
- A facile synthesis of bicyclo[m.n.1]alkan-1-ols. Evidence for organosamarium intermediates in the samarium(II) iodide promoted intramolecular Barbier-type reactionThe Journal of Organic Chemistry, 1991