Charge-transfer luminescence from mixed-ligand, 2,2′,2″-terpyridine–phosphine, complexes of osmium(II)
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 793-795
- https://doi.org/10.1039/c39810000793
Abstract
The first example of intense room temperature charge-transfer (CT) emission from a series of metal-terpyridine complexs {[OsII(trpy)(diphosph)L]n+(trpy = 2,2′,2″-terpyridine and diphosph is, e.g., Ph2PCH2PPh2)} in fluid solution is reported; the complexes can have relatively long CT excited-state lifetime while also exhibiting substitutional photochemistry.Keywords
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